Synthesis and structural characterization of a novel magnesium β-diketonatoalkoxide complex: a new precursor for the MOCVD of MgO

被引：0

作者：

Davies, H.O. ^{[1
]}

Jones, A.C. ^{[2
]}

Leedham, T.J. ^{[3
]}

Crosbie, M.J. ^{[1
]}

Wright, P.J. ^{[3
]}

Boag, N.M. ^{[1
]}

Thompson, J.R. ^{[2
]}

机构：

[1] Inorgtech Limited, 25 James Carter Road, Mildenhall, Suffolk IP28 7DE, United Kingdom

[2] Defence, Evaluation and Research Agency, St. Andrews Road, Worcestershire WR14 3PS, United Kingdom

[3] Department of Chemistry, University of Salford, Salford M5 4WT, United Kingdom

来源：

Advanced Materials | 2000年 / 12卷 / 07期

关键词：

Auger electron spectroscopy - Carbon - Film growth - High temperature operations - Magnesium compounds - Structure (composition) - Synthesis (chemical) - Thin films - X ray crystallography;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The tetrameric magnesium complex [Mg(thd)(μ3-OMe)(MeOH)]4 (thd = 2,2,6,6-tetramethylheptane-3,5-dionate), 1, has been synthesized and its structure determined by X-ray crystallography. Thin films of magnesium oxide, MgO, have been deposited by liquid-injection MOCVD using tetrahydrofuran solutions of 1. The films were deposited at substrate temperatures of between 500 and 600°C and, under optimum growth conditions, were shown by Auger electron spectroscopy to be pure magnesium oxide with no detectable carbon.

引用

页码：71 / 75

共 50 条

[31] Synthesis, Characterization, and Mass Transport Properties of a Self-Generating Single-Source Magnesium Precursor for MOCVD of MgF2 Films
Fragala, Maria E.
Toro, Roberta G.
Rossi, Patrizia
Dapporto, Paolo
Malandrino, Graziella
CHEMISTRY OF MATERIALS, 2009, 21 (10) : 2062 - 2069
[32] SYNTHESIS AND CHARACTERIZATION OF SPHERE-LIKE ZnS NANOCRYSTALS BY THERMOLYSIS OF A NEW COMPLEX PRECURSOR
Zhang, Jianjun
Duan, Junhong
MODERN PHYSICS LETTERS B, 2010, 24 (19): : 2091 - 2099
[33] Synthesis and Structural Characterization of a New Cadmium(II) Complex with a Double Betaine
ZHENG Fa-Kuna② WU A-Qinga
Chinese Journal of Structural Chemistry, 2005, (08) : 940 - 944
[34] Synthesis and structural characterization of a new tetranuclear macrocyclic copper(I) complex
Utz, D
Heinemann, FW
Mukherjee, J
Mukherjee, R
Schindler, S
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (12-13): : 2211 - 2215
[35] Synthesis and Structural Characterization of a New Cadmium(II) Complex with a Double Betaine
ZHENG FaKuna WU AQinga b LI Yana b GUO GuoConga HUANG JinShuna a State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China b Graduate School The Chinese Academy of Sciences Beijing China
结构化学, 2005, (08) : 940 - 944+862
[36] Synthesis and structural characterization of a new cadmium(II) complex with a double betaine
Zheng, FK
Wu, AQ
Li, Y
Guo, GC
Huang, JS
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (08) : 940 - 944
[37] Thermochemical investigation of perspective MOCVD precursor of MgO functional layersBis-(trifluoroacetylacetonato)(N,N,N′,N′-tetramethylethylenediamine)magnesium(II)
Evgeniia S. Vikulova
Kseniya V. Zherikova
Sergey V. Sysoev
Asiya E. Turgambaeva
Sergey V. Trubin
Natalia B. Morozova
Igor K. Igumenov
Journal of Thermal Analysis and Calorimetry, 2019, 137 : 923 - 930
[38] Synthesis and characterization of a new organotin(IV) complex as a new precursor for preparation SnO2 nanoparticles
Amini, Mostafa M.
Najafi, Ezzatollah
Karami, Behzad
Khavasi, Hamidreza
INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (03) : 332 - 339
[39] Synthesis and characterization of MgO nanowires through a vapor-phase precursor method
Yin, YD
Zhang, GT
Xia, YN
ADVANCED FUNCTIONAL MATERIALS, 2002, 12 (04) : 293 - 298
[40] Solvothermal synthesis and structural characterization of a novel erbium(III)-carboxylate polymeric complex
Bo, Q. B.
Sun, Z. X.
Sheng, Y. L.
Zhang, Z. W.
Sun, G. X.
Chen, C. L.
Li, Y. X.
Wang, D. Q.
STRUCTURAL CHEMISTRY, 2006, 17 (06) : 609 - 615

← 1 2 3 4 5 →