Structural characteristics of 2212-phase single crystal in the Bi-Sr-Ca-Cu-O superconductor

被引:0
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作者
Guien, Zhou [1 ]
Lei, Shi [1 ]
Yunlan, Huang [1 ]
Yunbo, Jia [1 ]
Jiang, Lu [1 ]
Genda, Gu [1 ]
Weili, Cai [1 ]
Yaozhong, Ruan [1 ]
Yuheng, Zhang [1 ]
机构
[1] Univ of Science and Technology of, China, Hefei, China
关键词
Bismuth compounds - Ceramic materials - Crystal structure;
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摘要
A single crystal of Bi-Sr-Ca-Cu-O 2212 superconducting phase has been studied by combining the Laue method with the method of X-ray diffractometry. It is suggested that the single-crystal structure of a superconductor is a modulated structure of a three-dimensional period coexisting with a two-dimensional lattice. In the structure, the Bi-concentrated bands, which form a three-dimensional modulated structure that corresponds to the results observed in high-resolution electron microscopy, do not entirely enter the parent structure lattice, but divide the parent structure into oxygen-deficient pervoskitelike layers. The pervoskitelike layer has a quasi-two-dimensional structure. The element modulation of Sr and Ca appears in the two-dimensional lattice, which is caused by the effect of Bi-concentrated bands. Meanwhile, the superlattice is formed on the ab plane. The three-dimensional structure of periodic modulation is formed by the pervoskitelike layer and Bi-concentrated band as a unit.
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页码:774 / 777
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