Preparation of the high-Tc phase of Bi-Sr-Ca-Cu-O superconductor

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作者
Endo, Utako [1 ]
Koyama, Satoshi [1 ]
Kawai, Tomoji [1 ]
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[1] Daikin Industries Ltd, Japan
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Bismuth Compounds - Ceramic Materials - Semiconductor Materials - X-Rays - Diffraction;
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摘要
Co-decomposition of mixed nitrates of Bi, Pb, Sr, Ca and Cu around 830°C under low oxygen pressure led to the formation of a high-Tc superconducting phase of Bi(Pb)-Sr-Ca-Cu-O with Tc(zero) at 107.5 K. A sample prepared by a conventional solid state reaction method under low oxygen pressure also showed the superconducting transition at 107.5 K. X-ray powder diffraction and magnetic susceptibility measurements on these samples revealed the high-Tc phase without 80 K or semiconducting phase. The reaction under low oxygen pressure has an effect to lower the temperature with broad ranges to render the high-Tc phase of the Bi-Sr-Ca-Cu-O.
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