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Vanadium-catalyzed cross-coupling reactions of alkyl halides with aryl grignard reagents
被引:0
|作者:
Yasuda, Shigeo
[1
]
Yorimitsu, Hideki
[1
]
Oshima, Koichiro
[1
]
机构:
[1] Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
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关键词:
Vanadium(III) chloride catalyzed cross-coupling reactions of alkyl halides with arylmagnesium bromides. Various arylmagnesium bromides;
except for an ortho-substituted arylmagnesium reagent;
could be used for the reaction. Among alkyl halides tested;
cyclohexyl halides and primary alkyl halides were good substrates. The reactions likely proceed via carbon-centered radical intermediates. ©2008 The Chemical Society of Japan;
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Journal article (JA)
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页码:287 / 290
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