The shift in chemical potential of electrons upon intercalation of ZrSe2 by copper

被引：0

作者：

Shkvarin, A. S. ^{[1
]}

Suslov, E. A. ^{[1
]}

Postnikov, M. S. ^{[1
]}

Titov, A. N. ^{[1
]}

机构：

[1] Russian Acad Sci, MN Miheev Inst Met Phys, Ural Branch, Ekaterinburg 620990, Russia

来源：

MATERIALS LETTERS | 2025年 / 379卷

关键词：

EMF; XPS; Bidning ebergy; Fermy level; Chemical shift; SOLVENT;

D O I：

10.1016/j.matlet.2024.137673

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The effective valence of copper in the region of its concentration up to x = 0.25 in CuxZrSe2 has been determined based on an analysis of binding energies of the Zr3d and Se3d core levels and the electromotive forces from an electrochemical experiment for CuxZrSe2, as a function of Cu concentration x. It has been shown that the domination of covalent bonding between copper and the ZrSe2 host lattice within this concentration range results in a notable reduction in the effective valence of copper in comparison to its nominal value.

引用

页数：3

共 49 条

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