TI4+/TI3+ AND TI3+/TI2+ REDOX POTENTIAL DEPENDENCE UPON THE CHEMICAL NATURE OF THE MELTED ELECTROLYTE MADE UP OF ALKALI AND ALKALI-EARTH CHLORIDES

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作者：
ENE, N
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来源：
REVISTA DE CHIMIE | 1994年 / 45卷 / 12期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The electrochemical behaviour of Ti+4/Ti+3 and Ti3+/Ti2+ redox couples in molten electrolytes, consisting of mixtures of alkali and alkali chlorhides, is described. A dependence of formal electrode potential on the chemical nature and concentration of alkali earth cation was noted in these electrolytes, which point to an enhanced solvent-solute interaction. This interaction turns stronger in the sequence Ba>Sr>Ca>Mg.
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页码：1076 / 1080
页数：5
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