Thermodynamic Properties of Gadolinium Titanate Gd2Ti2O7

被引：0

作者：

Gagarin, P. G. ^{[1
]}

Guskov, A. V. ^{[1
]}

Guskov, V. N. ^{[1
]}

Khoroshilov, A. V. ^{[1
]}

Gavrichev, K. S. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119071, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2024年 / 98卷 / 11期

关键词：

RE titanates; heat capacity; thermodynamics; phase transition; PYROCHLORE ANTIFERROMAGNET; FORMATION ENTHALPIES; EARTH TITANATES; HEAT-CAPACITIES; LATTICE;

D O I：

10.1134/S0036024424701620

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The isobaric heat capacity of pyrochlore gadolinium titanate Gd2Ti2O7 is measured in the 2-1825 K range of temperatures. Thermodynamic functions (entropy, enthalpy change, reduced Gibbs energy) are calculated using consistent smoothed values of heat capacity. The Gibbs energy of the formation of Gd2Ti2O7 from oxides in the high temperature range is estimated.

引用

页码：2453 / 2460

页数：8

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