Synthesis of Nanocrystalline Gd2Ti2O7 by Combustion Process and its Structural, Optical and Dielectric Properties

Nanosized pyrochlore material Gadolinium Titanate (Gd2Ti2O7) powder was prepared by modified single step auto-ignition combustion process. The phase formation has been investigated using X-Ray diffraction analysis (XRD). The crystalline pyrochlore phase is further confirmed by the presence of metal-oxygen bonds in the FT-IR spectra. XRD analysis revealed that Gd2Ti2O7 has a cubic structure With Fd3m space group. The combustion powder was sintered to high density (97% of theoretical density) at similar to 1300 degrees C for 4h and the surface morphology was examined by Scanning Electron Microscopy (SEM). The optical band gap of Gd2Ti2O7 determined from the absorption spectrum is found to be 4.2 eV, which corresponds to direct allowed transitions. The dielectric measurements were carried out using LCR meter in the radio frequency region at room temperature. The sintered Gd2Ti2O7 has a dielectric constant (epsilon(r)) = 40 and dielectric loss (tan delta) = 0.01 at 1 MHz.