Application of HfSiON to deep-trench capacitors of sub-45-nm-node embedded dynamic random-access memory

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作者
Ando, Takashi [1 ]
Sato, Naoyuki [1 ]
Hiyama, Susumu [1 ]
Hirano, Tomoyuki [1 ]
Nagaoka, Kojiro [1 ]
Abe, Hitoshi [1 ]
Okuyama, Atsushi [1 ]
Ugajin, Hajime [1 ]
Tai, Kaori [1 ]
Fujita, Shigeru [1 ]
Watanabe, Koji [1 ]
Katsumata, Ryota [2 ]
Idebuchi, Jun [3 ]
Suzuki, Takashi [3 ]
Hasegawa, Toshiaki [1 ]
Iwamoto, Hayato [1 ]
Kadomura, Shingo [1 ]
机构
[1] Semiconductor Technology Development Group, Semiconductor Solutions Network Company, Sony Corporation, 4-14-1 Asahi-cho, Atsugi, Kanagawa 243-0014, Japan
[2] SoC R and D Center, 8 Shinsugita, Isogo-ku, Yokohama 235-8522, Japan
[3] Process and Manufacturing Engineering Center, Semiconductor Company, Toshiba Corporation, 8 Shinsugita, Isogo-ku, Yokohama 235-8522, Japan
关键词
In this study; the potential of HfSiON as the node dielectric of deep-trench (DT) capacitors was investigated for the first time. It was found out that a uniform thickness and a uniform depth profile of each component in DT can be obtained by the ALD process which utilizes the catalytic effect of the Hf precursor and Si precursor. In addition; the mechanism underlying leakage current was analyzed and it was revealed that residual carbons in the film contribute to the Poole-Frenkel current through the film. On the basis of these findings; we propose the sequential high-pressure ozone treatment (SHO) and Al2O3/HfSiON/ Si3N4 stack for DT applications. Finally; the DT capacitors of 65-nm-node embedded dynamic random-access memory (eDRAM) were fabricated and a capacitance enhancement of 50% from the conventional dielectric (NO) was obtained at the same leakage current. ©2006 The Japan Society of Applied Physics;
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页码:3165 / 3169
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