Effects of structural variables on AUL and rheological behavior of SAP gels

被引：0

作者：

Ramazani-Harandi, M.J. ^{[1
]}

Zohuriaan-Mehr, M.J. ^{[1
]}

Yousefi, A.A. ^{[1
]}

Ershad-Langroudi, A. ^{[1
]}

Kabiri, K. ^{[1
]}

机构：

[1] Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965-115, Tehran, Iran

来源：

Journal of Applied Polymer Science | 2009年 / 113卷 / 06期

关键词：

The swelling properties of superabsorbent polymers (SAPs) under real conditions are extremely important for selecting the material suitable for a. given application; e.g. feminine napkin; or agriculture. This new practical research represents deeper synthetic and physicochemical studies on the structure-property relation in acrylic SAP hydrogels and composites. Thus; the values of saline-absorbency under load (AUL; a measurable simulation of the real circumstances of SAP applications; at pressures 0.3-0.9 psi) were measured for the SAP or SAP composite samples prepared under different conditions; i.e. type and content of crosslinker; type and concentration of initiator; percentage of inorganic filler (kaolin); and type and percentage of porosity generators. The samples were subsequently used to determine the rheological and morphological characteristics. Dynamic storage modulus (G') measurements were carried out at constant strain; in. a wide range of frequency. Linear correlations were frequently found to be active between AUL and G data over the rubber-elastic plateau. Thus; for a given SAP: AUL = KtotalG' + C. The coefficient k total is a function of (nature and content of crosslinker; initiator; inorganic component; particle morphology; etc.); Therefore; the easily measured AUL values could be simply correlated to the main synthesis variables and molecular structure of SAP gels through a rheological material function (G'). © 2009 Wiley Periodicals; Inc;

D O I：

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学科分类号：

摘要：

Journal article (JA)

引用

页码：3676 / 3686

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