The synthesis of water-soluble poly(o-phenylenediamine) and solid electrochromic device

被引：0
|
作者：
Research Institute of Applied Chemistry, College of Chemistry and Chemical Engineering, Southwest China University, Chongqing 400715, China [1 ]
不详 [2 ]
不详 [3 ]
机构：
来源：
Gongneng Cailiao | 2009年 / SUPPL. 1卷 / 78-80期
关键词：
Ammonium persulfate - Complex film - Complex films - Cyclic voltammograms - Doping agent - Electrical conductivity - O- phenylenediamine - Poly (o-phenylenediamine) - Response time - Sodium polystyrene sulfonate - UV- and;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The water-soluble poly(o-phenylenediamine) was synthesized by chemically xxidative polymerization with ammonium persulfate as oxidant, sodium polystyrene sulfonate as template doping agent, o-phenylenediamine as monomer. The effect of dosage of oxidant to its electrical conductivity was discussed, its structure and electrochemical capability was tested by IR, UV and cyclic voltammogram, and a simple solid electrochromic device was assembled with PoPD/ PSS complex, it was found that the fastest of its response time was 1-2 and the lowest voltage was 0.9V which was likely to be used in environmental electrochromic devices.
引用
收藏
相关论文
共 50 条
  • [31] Integrated Synthesis of Poly(o-phenylenediamine)-Derived Carbon Materials for High Performance Supercapacitors
    Zhu, Hui
    Wang, Xiaolei
    Liu, Xuexia
    Yang, Xiurong
    ADVANCED MATERIALS, 2012, 24 (48) : 6524 - 6529
  • [32] REDOX REACTION OF PEROXIDASE AT POLY(O-PHENYLENEDIAMINE) MODIFIED ELECTRODE
    DENG, Q
    DONG, SJ
    ELECTROANALYSIS, 1994, 6 (10) : 878 - 881
  • [33] Synthesis and electrochromic properties of a highly water-soluble hyperbranched polymer viologen
    Sakano, Takeshi
    Ito, Fuyuki
    Ono, Tomonori
    Hirata, Osamu
    Ozawa, Masaaki
    Nagamura, Toshihiko
    THIN SOLID FILMS, 2010, 519 (04) : 1458 - 1463
  • [34] Electrosynthesis of poly(o-phenylenediamine) in a room temperature ionic liquid
    Zane, D.
    Raffaele, A.
    Curulli, A.
    Appetecchi, G. B.
    Passerini, S.
    ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (08) : 2037 - 2040
  • [35] STRUCTURE-PROPERTY RELATIONSHIPS IN POLY(O-PHENYLENEDIAMINE) DERIVATIVES
    GOYETTE, MA
    LECLERC, M
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 382 (1-2) : 17 - 23
  • [36] Association constant of conductive poly(o-phenylenediamine) with halogenide ions
    Yano, J
    Nagaoka, T
    SYNTHETIC METALS, 1997, 84 (1-3) : 271 - 272
  • [37] Electrochemical activity and microscopy of electrosynthesised poly(o-phenylenediamine) nanotubes
    Alina Prună
    Florina Brânzoi
    Journal of Polymer Research, 2012, 19
  • [38] Electrosynthesis of poly( o-phenylenediamine) in ionic liquid and its properties
    DU YanFang
    Chinese Science Bulletin, 2007, (16) : 2174 - 2178
  • [39] Density Functional Theory Study of Poly(o-phenylenediamine) Oligomers
    Ullah, Habib
    Shah, Anwar-ul-Haq Ali
    Ayub, Khurshid
    Bilal, Salma
    JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (08): : 4069 - 4078
  • [40] Electrochemical activity and microscopy of electrosynthesised poly(o-phenylenediamine) nanotubes
    Pruna, Alina
    Branzoi, Florina
    JOURNAL OF POLYMER RESEARCH, 2012, 19 (06)
12345