The synthesis of water-soluble poly(o-phenylenediamine) and solid electrochromic device

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作者：
Research Institute of Applied Chemistry, College of Chemistry and Chemical Engineering, Southwest China University, Chongqing 400715, China [1 ]
不详 [2 ]
不详 [3 ]
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来源：
Gongneng Cailiao | 2009年 / SUPPL. 1卷 / 78-80期
关键词：
Ammonium persulfate - Complex film - Complex films - Cyclic voltammograms - Doping agent - Electrical conductivity - O- phenylenediamine - Poly (o-phenylenediamine) - Response time - Sodium polystyrene sulfonate - UV- and;
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摘要：
The water-soluble poly(o-phenylenediamine) was synthesized by chemically xxidative polymerization with ammonium persulfate as oxidant, sodium polystyrene sulfonate as template doping agent, o-phenylenediamine as monomer. The effect of dosage of oxidant to its electrical conductivity was discussed, its structure and electrochemical capability was tested by IR, UV and cyclic voltammogram, and a simple solid electrochromic device was assembled with PoPD/ PSS complex, it was found that the fastest of its response time was 1-2 and the lowest voltage was 0.9V which was likely to be used in environmental electrochromic devices.
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