Two amino-functionalized metal-organic frameworks with different topologies for C2H2/C2H4 separation

被引：0
|
作者：
Li, Yue [1 ]
Xu, Mingming [1 ]
Liu, Hongyan [1 ]
Wang, Xiaokang [1 ]
Wang, Yutong [1 ]
Sun, Meng [1 ]
Fan, Weidong [1 ,2 ]
Sun, Daofeng [1 ,2 ]
机构：
[1] China Univ Petr East China, Sch Mat Sci & Engn, Qingdao 266580, Shandong, Peoples R China
[2] China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China
来源：
DALTON TRANSACTIONS | 2024年 / 53卷 / 45期
基金：
中国国家自然科学基金;
关键词：
CONSTRUCTION; ADSORPTION; DESIGN;
D O I：
10.1039/d4dt02592j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The rational design of metal-organic framework adsorbents is crucial for target gas separation. Herein, we report two three-dimensional MOFs with different topologies by regulating metal ions with amino-functionalized V-type ligands. Adsorption isotherms and Grand Canonical Monte Carlo simulation reveal that UPC-122 with channel-cavity structure has the potential to separate C2H2/C2H4 at room temperature with a separation ratio of 2.35 (50/50).
引用
收藏
页码：18094 / 18098
页数：5
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