Two amino-functionalized metal-organic frameworks with different topologies for C2H2/C2H4 separation

被引：0
|
作者：
Li, Yue [1 ]
Xu, Mingming [1 ]
Liu, Hongyan [1 ]
Wang, Xiaokang [1 ]
Wang, Yutong [1 ]
Sun, Meng [1 ]
Fan, Weidong [1 ,2 ]
Sun, Daofeng [1 ,2 ]
机构：
[1] China Univ Petr East China, Sch Mat Sci & Engn, Qingdao 266580, Shandong, Peoples R China
[2] China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China
来源：
DALTON TRANSACTIONS | 2024年 / 53卷 / 45期
基金：
中国国家自然科学基金;
关键词：
CONSTRUCTION; ADSORPTION; DESIGN;
D O I：
10.1039/d4dt02592j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The rational design of metal-organic framework adsorbents is crucial for target gas separation. Herein, we report two three-dimensional MOFs with different topologies by regulating metal ions with amino-functionalized V-type ligands. Adsorption isotherms and Grand Canonical Monte Carlo simulation reveal that UPC-122 with channel-cavity structure has the potential to separate C2H2/C2H4 at room temperature with a separation ratio of 2.35 (50/50).
引用
收藏
页码：18094 / 18098
页数：5
相关论文
共 50 条
  • [21] Efficient C2H2/CO2 and C2H2/C2H4 separations in a novel fluorinated metal-organic framework
    Han, Yan
    Jiang, Yunjia
    Hu, Jianbo
    Wang, Lingyao
    Zhang, Yuanbin
    SEPARATION AND PURIFICATION TECHNOLOGY, 2024, 332
  • [22] Simultaneous Trapping of C2H2 and C2H6 from a Ternary Mixture of C2H2/C2H4/C2H6 in a Robust Metal-Organic Framework for the Purification of C2H4
    Hao, Hong-Guo
    Zhao, Yun-Feng
    Chen, Di-Ming
    Yu, Jia-Mei
    Tan, Kui
    Ma, Shengqian
    Chabal, Yves
    Zhang, Zhi-Ming
    Dou, Jian-Min
    Xiao, Zi-Hui
    Day, Gregory
    Zhou, Hong-Cai
    Lu, Tong-Bu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (49) : 16067 - 16071
  • [23] Rational Pore Design in Multivariate Metal-Organic Frameworks for C2H6/C2H4 Separation
    Park, Jihyun
    Oh, Kwang Hyun
    Kang, Shinyoung
    Ha, Junsu
    Lee, Seungjin
    Kim, Jihan
    Bae, Youn-Sang
    Moon, Hoi Ri
    SMALL, 2025,
  • [24] A thermostable anion-pillared metal-organic framework for C2H2/C2H4 and C2H2/CO2 separations
    Jiang, Mengdie
    Cui, Xili
    Yang, Lifeng
    Yang, Qiwei
    Zhang, Zhiguo
    Yang, Yiwen
    Xing, Huabin
    CHEMICAL ENGINEERING JOURNAL, 2018, 352 : 803 - 810
  • [25] An anion-functionalized zinc-organic framework for efficient C2H2/C2H4 separation
    Zou, Shuixiang
    Di, Zhengyi
    Liu, Yuanzheng
    Ji, Zhenyu
    Li, Hengbo
    Chen, Cheng
    Wu, Mingyan
    INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 137
  • [26] Inverse design of metal–organic frameworks for C2H4/C2H6 separation
    Musen Zhou
    Jianzhong Wu
    npj Computational Materials, 8
  • [27] Achieving Record C2H2 Packing Density for Highly Efficient C2H2/C2H4 Separation with a Metal-Organic Framework Prepared by a Scalable Synthesis in Water
    Zhang, Xin
    Chen, Qiancheng
    Bai, Xuefeng
    Zhao, Yan-Long
    Li, Jian-Rong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (45)
  • [28] A robust metal-organic framework for simultaneous C2H4/C3H6 capture and C2H2/CO2 separation
    Chen, Yang
    Yang, Dongxiao
    Wang, Yi
    Shi, Qi
    Tang, Bo
    Zhu, Chongqin
    Li, Jinping
    Li, Libo
    FUEL, 2024, 368
  • [29] Efficient C2H2/CO2 Separation in Ultramicroporous Metal-Organic Frameworks with Record C2H2 Storage Density
    Gong, Wei
    Cui, Hui
    Xie, Yi
    Li, Yingguo
    Tang, Xianhui
    Liu, Yan
    Cui, Yong
    Chen, Banglin
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (36) : 14869 - 14876
  • [30] Metal-organic frameworks for C2H2/CO2 separation: Recent development
    Wang, Xiaokang
    Liu, Hongyan
    Li, Yue
    Yang, Xinlei
    Gao, Fei
    Wang, Xiaoqing
    Kang, Zixi
    Fan, Weidong
    Sun, Daofeng
    COORDINATION CHEMISTRY REVIEWS, 2023, 482
12345