Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

被引：0

作者：

Han S.-D. ^{[1
]}

Zhang X.-R. ^{[1
]}

Pan J. ^{[1
]}

Mu Y. ^{[1
]}

Li J.-H. ^{[1
]}

Wang G.-M. ^{[1
]}

机构：

[1] College of Chemistry and Chemical Engineering, Qingdao University, Shandong

来源：

Wang, Guo-Ming (gmwang_pub@163.com) | 2018年 / Royal Society of Chemistry卷 / 47期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1039/C8DT02761G

中图分类号：

学科分类号：

摘要：

Two zinc-phosphites modified by a rigid amine 3,5-bis(imidazole-1-yl)pyridine (BIP), [Zn2(HPO3)2(BIP)]·H2O (1) and [Zn3(HPO3)3(BIP)(H2O)]·H2O (2), were solvothermally prepared. Compound 1 possesses a zincophosphite layer decorated by BIP moieties via coordinating to intralayer Zn(ii) ions. Compound 2 features a 3D frame with a pillar-layer structure, in which the organic BIP pillars the inorganic zincophosphite layer via coordinating to interlayer Zn(ii) ions. The structural diversity from a 2D layer to a 3D frame was mainly attributable to the different bridging modes of BIP in the process of assembly. Their temperature-dependent photoluminescence properties have also been studied. © The Royal Society of Chemistry.

引用

页码：12468 / 12473

页数：5

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