Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties

被引：0
|
作者：
Han S.-D. [1 ]
Zhang X.-R. [1 ]
Pan J. [1 ]
Mu Y. [1 ]
Li J.-H. [1 ]
Wang G.-M. [1 ]
机构：
[1] College of Chemistry and Chemical Engineering, Qingdao University, Shandong
来源：
Wang, Guo-Ming (gmwang_pub@163.com) | 2018年 / Royal Society of Chemistry卷 / 47期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1039/C8DT02761G
中图分类号：
学科分类号：
摘要：
Two zinc-phosphites modified by a rigid amine 3,5-bis(imidazole-1-yl)pyridine (BIP), [Zn2(HPO3)2(BIP)]·H2O (1) and [Zn3(HPO3)3(BIP)(H2O)]·H2O (2), were solvothermally prepared. Compound 1 possesses a zincophosphite layer decorated by BIP moieties via coordinating to intralayer Zn(ii) ions. Compound 2 features a 3D frame with a pillar-layer structure, in which the organic BIP pillars the inorganic zincophosphite layer via coordinating to interlayer Zn(ii) ions. The structural diversity from a 2D layer to a 3D frame was mainly attributable to the different bridging modes of BIP in the process of assembly. Their temperature-dependent photoluminescence properties have also been studied. © The Royal Society of Chemistry.
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页码：12468 / 12473
页数：5
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