A 3D open-framework amino acid templated cerium phosphite-oxalate showing proton conductive property

被引：1
|
作者：
Li, Honglu [1 ]
Huang, Liangliang [1 ]
Lu, Yang [1 ]
Zhao, Shanshan [1 ]
Shao, Xin [1 ]
Bi, Yanfeng [1 ]
机构：
[1] Liaoning Petrochem Univ, Sch Petrochem Engn, Fushun 113001, Liaoning, Peoples R China
来源：
SOLID STATE SCIENCES | 2024年 / 157卷
关键词：
Hydrothermal synthesis; Open-framework; Crystal structure; Cerium phosphite-oxalate; Proton conductivity; ZINC PHOSPHITE; NETWORKS;
D O I：
10.1016/j.solidstatesciences.2024.107692
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Using L-histidine as template, a three-dimensional (3D) open-framework cerium phosphite-oxalate, Ce-2(H2O)(2)(H2PO3)(2)(C2O4)(3)center dot C6H11N3O2 center dot H2O (1), has been synthesized under hydrothermal condition. Interestingly, it is the first example of lanthanide phosphite-oxalate with amino acid as the template. Compound 1 shows 3D framework with 8-, 12- and 20-ring channels and has a mog Moganite topology. A large amount of free water molecules and histidine cations are located in the channels of 1, which are favorable to the efficient proton transfer. Correspondingly, compound 1 displays temperature and humidity dependent proton conductivity with the highest value of 3.67 x 10(-4) S cm(-1) at 75 degree celsius and 98 % RH.
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页数：5
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