Photocatalytic Three-Component Acylcarboxylation of Alkenes with CO2

被引：3

作者：

Watanabe, Taito ^{[1
]}

Lorwongkamol, Phurinat ^{[1
]}

Saga, Yutaka ^{[1
,4
]}

Kosugi, Kento ^{[1
,2
]}

Kambe, Tetsuya ^{[1
,3
]}

Kondo, Mio ^{[1
,2
,4
]}

Masaoka, Shigeyuki ^{[1
,4
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Div Appl Chem, Suita, Osaka 5650871, Japan

[2] Tokyo Inst Technol, Sch Sci, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

[3] Osaka Univ, Fac Engn, Ctr Future Innovat CFi, Dept Appl Chem, Suita, Osaka 5650871, Japan

[4] Osaka Univ, Inst Open & Transdisciplinary Res Initiat ICS OTRI, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 30期

基金：

日本科学技术振兴机构; 日本学术振兴会;

关键词：

PHOTOREDOX-CATALYZED DICARBOFUNCTIONALIZATION; GAMMA-KETO ACIDS; AMINO-ACIDS; STYRENES; ECONOMY; ESTERS; ATOM;

D O I：

10.1021/acs.orglett.4c02295

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

gamma-Keto acid is a valuable chemical motif in a wide range of fields including organic, biological, and medicinal chemistry. However, its single-step synthesis is challenging because of the mismatch of the carbonyl polarity and low tolerance of carboxylic acids. Herein, we report the single-step syntheses of gamma-keto acids using alkenes and CO2. Our photocatalytic system enabled the transformation of alkenes under mild conditions in high yields (up to 95%) with broad substrate generality (35 examples).

引用

页码：6491 / 6496

页数：6

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