Rhodium-Catalyzed Asymmetric Suzuki and Related Cross-Coupling Reactions

被引：0
|
作者：
Webster, Stephen [1 ]
Cunningham, Laura [1 ]
Fletcher, Stephen P. [1 ]
机构：
[1] Univ Oxford, Chem Res Lab, Dept Chem, Oxford OX1 3TA, England
来源：
ALDRICHIMICA ACTA | 2024年 / 57卷 / 01期
关键词：
enantioselective; rhodium; cross-coupling; asymmetric catalysis; allylic arylation; hydroarylation; Suzuki-Mi-; yaura; enantioconvergence; Dynamic Kinetic Asymmetric Transformation (DYKAT); boronic acids; ENANTIOSELECTIVE DESYMMETRIZATION; ALLYLIC SUBSTITUTION; NUCLEOPHILES; ARYLATION; REAGENTS; ACIDS;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We describe in this account our progress towards the development of new catalytic asymmetric cross -coupling reactions. We focus on the application of boronic acids in the synthesis of enantioenriched C(sp (2) )-C(sp (3) ) coupled products from prochiral and racemic starting materials. Specifically, we describe the rhodium -catalyzed Suzuki-Miyaura-type arylations of allylic halides and cyclobutenes, their key mechanistic features, and their applications to complex -molecule synthesis and scale -up.
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页数：32
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