Rhodium-Catalyzed Asymmetric Suzuki and Related Cross-Coupling Reactions

被引：0

作者：

Webster, Stephen ^{[1
]}

Cunningham, Laura ^{[1
]}

Fletcher, Stephen P. ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Dept Chem, Oxford OX1 3TA, England

来源：

ALDRICHIMICA ACTA | 2024年 / 57卷 / 01期

关键词：

enantioselective; rhodium; cross-coupling; asymmetric catalysis; allylic arylation; hydroarylation; Suzuki-Mi-; yaura; enantioconvergence; Dynamic Kinetic Asymmetric Transformation (DYKAT); boronic acids; ENANTIOSELECTIVE DESYMMETRIZATION; ALLYLIC SUBSTITUTION; NUCLEOPHILES; ARYLATION; REAGENTS; ACIDS;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe in this account our progress towards the development of new catalytic asymmetric cross -coupling reactions. We focus on the application of boronic acids in the synthesis of enantioenriched C(sp (2) )-C(sp (3) ) coupled products from prochiral and racemic starting materials. Specifically, we describe the rhodium -catalyzed Suzuki-Miyaura-type arylations of allylic halides and cyclobutenes, their key mechanistic features, and their applications to complex -molecule synthesis and scale -up.

引用

页数：32

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