Activated Carbon Derived from Cucumber Peel for Use as a Supercapacitor Electrode Material

被引:0
|
作者
Nazhipkyzy, Meruyert [1 ,2 ,3 ]
Kurmanbayeva, Gulim [2 ]
Seitkazinova, Aigerim [1 ,2 ]
Varol, Esin Apaydin [4 ]
Li, Wanlu [5 ]
Dinistanova, Balaussa [1 ]
Issanbekova, Almagul [2 ,6 ]
Mashan, Togzhan [7 ]
机构
[1] Al Farabi Kazakh Natl Univ, Dept Chem Phys & Mat Sci, 71 Al-Farabi Ave, Alma Ata 050038, Kazakhstan
[2] Inst Combust Problems, Bogenbai Batyr St 172, Alma Ata 050012, Kazakhstan
[3] Satbayev Univ, Dept Mat Sci Nanotechnol & Engn Phys, Satpaev St 22, Alma Ata 050000, Kazakhstan
[4] Eskisehir Tech Univ, Dept Chem Engn, TR-26555 Eskisehir, Turkiye
[5] Montclair State Univ, Dept Chem & Biochem, 1 Normal Ave, Montclair, NJ 07043 USA
[6] Al Farabi Kazakh Natl Univ, UNESCO Chair Sustainable Dev, 71 Al Farabi Ave, Alma Ata 050038, Kazakhstan
[7] LN Gumilyov Eurasian Natl Univ, Dept Chem, Kazhymukan Str 11, Astana 010000, Kazakhstan
关键词
biowaste; capacitive performance; porous carbon; pore accessibility; cucumber peels; COCONUT-SHELL; POROUS CARBON; ORANGE PEEL; HIGH-ENERGY; PERFORMANCE; SURFACE; FABRICATION; CAPACITORS; NANOSHEETS; POROSITY;
D O I
10.3390/nano14080686
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Biowaste conversion into activated carbon is a sustainable and inexpensive approach that relieves the pressure on its disposal. Here, we prepared micro-mesoporous activated carbons (ACs) from cucumber peels through carbonization at 600 degrees C followed by thermal activation at different temperatures. The ACs were tested as supercapacitors for the first time. The carbon activated at 800 degrees C (ACP-800) showed a high specific capacitance value of 300 F/g at a scan rate of 5 mV/s in the cyclic voltammetry and 331 F/g at the current density of 0.1 A/g in the galvanostatic charge-discharge analysis. At the current density of 1 A/g, the specific discharge capacitance was 286 F/g and retained 100% capacity after 2000 cycles. Their properties were analyzed by scanning electron microscopy, energy-dispersive X-ray analysis, porosity, thermal analysis, and Fourier-transform infrared spectroscopy. The specific surface area of this sample was calculated to be 2333 m2 g-1 using the Brunauer-Emmett-Teller method. The excellent performance of ACP-800 is mainly attributed to its hierarchical porosity, as the mesopores provide connectivity between the micropores and improve the capacitive performance. These electrochemical properties enable this carbon material prepared from cucumber peels to be a potential source for supercapacitor materials.
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页数:15
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