SYNTHESIS AND STRUCTURE OF A COPPER(II) COMPLEX BASED ON N-2-(2-PYRIDYL)ETHYL-2-AMINOETHANESULFONIC ACID

被引：0

作者：

Zemlyakova, E. O. ^{[2
]}

Zharkov, G. P. ^{[1
]}

Petrova, Y. S. ^{[1
]}

Neudachina, L. K. ^{[1
]}

Slepukhin, P. A. ^{[2
]}

Aksenova, T. V. ^{[1
]}

Pestov, A. V. ^{[1
,2
]}

机构：

[1] Ural Fed Univ, Ekaterinburg, Russia

[2] Russian Acad Sci, Ural Branch, Postovsky Inst Organ Synth, Ekaterinburg, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2024年 / 65卷 / 07期

关键词：

copper(II) complexes; taurine N-derivatives; complexation; CRYSTAL-STRUCTURES; EFFICIENT LIGAND; CARBOXYLATE; SULFONATE; CATALYST;

D O I：

10.1134/S0022476624070102

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel copper(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid is prepared, its structure is studied by XRD (CCDC No. 2215117). The crystal of the complex is formed by monomeric [CuLH2O]NO3 units. The metal centers of the units have an octahedral coordination environment formed by nitrogen atoms of pyridine and the amino group, oxygen atoms of the sulfo group, and water molecules located in the equatorial plane. On the axial axis, there are oxygen atoms of the sulfo groups of the neighboring ligands forming a 1D coordination polymer.

引用

页码：1395 / 1403

页数：9

共 50 条

[41] Hydrothermal synthesis of a 2-(2-pyridyl)imidazole derivative and its copper(II) and zinc(II) complexes
Zhao, Chong-Chao
Ni, Wei-Wei
Yu, Ming-Ming
Cui, Ai-Li
Kou, Hui-Zhong
TRANSITION METAL CHEMISTRY, 2008, 33 (07) : 861 - 866
[42] Synthesis and electrochemical study of 2-(2-pyridyl)benzothiazole complexes with transition metals (CoII, NiII, and CuII). Molecular structure of aquabis[2-(2-pyridyl)benzothiazole]copper(II) diperchlorate
E. K. Beloglazkina
I. V. Yudin
A. G. Majouga
A. A. Moiseeva
A. I. Tursina
N. V. Zyk
Russian Chemical Bulletin, 2006, 55 : 1803 - 1809
[43] Di(2-pyridyl)phenylamine and (2-pyridyl)-N-piperidine
Wibaut, JP
Tilman, G
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS, 1933, 52 : 987 - 990
[44] 5-Ethyl-5-(2-pyridyl)-barbituric acid
McElvain, SM
Gorse, MA
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1943, 65 : 2226 - 2227
[45] Synthesis and electrochemical study of 2-(2-pyridyl)benzothiazole complexes with transition metals (CoII, NiII, and CuII).: Molecular structure of aquabis[2-(2-pyridyl)benzothiazole]copper(II) diperchlorate
Beloglazkina, E. K.
Yudin, I. V.
Majouga, A. G.
Moiseeva, A. A.
Tursina, A. L.
Zyk, N. V.
RUSSIAN CHEMICAL BULLETIN, 2006, 55 (10) : 1803 - 1809
[46] Hydrothermal synthesis of a 2-(2-pyridyl)imidazole derivative and its copper(II) and zinc(II) complexes
Chong-Chao Zhao
Wei-Wei Ni
Ming-Ming Yu
Ai-Li Cui
Hui-Zhong Kou
Transition Metal Chemistry, 2008, 33
[47] THE CRYSTAL-STRUCTURES OF BIS(2-AMINOETHYL 2-PYRIDYL SULFIDE)-COPPER(II) PERCHLORATE AND BIS(2-AMINOETHYL 2-PYRIDYL SULFOXIDE)-COPPER(II) PERCHLORATE
UMAKOSHI, K
KINOSHITA, I
MATSUMOTO, K
OOI, S
NIPPON KAGAKU KAISHI, 1986, (11) : 1517 - 1520
[48] Synthesis of N,N-bis[2-(2-pyridyl)ethyl]amino steroids and related compounds intended as chiral ligands for copper ions
Gonschior, M
Kötteritzsch, M
Rost, M
Schönecker, B
Wyrwa, R
TETRAHEDRON-ASYMMETRY, 2000, 11 (10) : 2159 - 2182
[49] 2-(2-PYRIDYL)PHENYL SELENIUM-COMPOUNDS - SYNTHESIS AND PROPERTIES - THE CRYSTAL-STRUCTURE OF 2-(2-PYRIDYL)PHENYL-SELENIUM(II) TRIBROMOMERCURATE(II)
MBOGO, SA
LOBANA, TS
MCWHINNIE, WR
GREAVES, MR
HAMOR, TA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 395 (02) : 167 - 175
[50] Synthesis and Crystal Structure of N-Benzyl-N'-(2-pyridyl)urea and Its Mononuclear Cu(Ⅱ) Complex
何磊
罗晓兰
张文勤
结构化学, 2008, (11) : 1384 - 1388

← 1 2 3 4 5 →