SYNTHESIS AND STRUCTURE OF A COPPER(II) COMPLEX BASED ON N-2-(2-PYRIDYL)ETHYL-2-AMINOETHANESULFONIC ACID

被引：0
|
作者：
Zemlyakova, E. O. [2 ]
Zharkov, G. P. [1 ]
Petrova, Y. S. [1 ]
Neudachina, L. K. [1 ]
Slepukhin, P. A. [2 ]
Aksenova, T. V. [1 ]
Pestov, A. V. [1 ,2 ]
机构：
[1] Ural Fed Univ, Ekaterinburg, Russia
[2] Russian Acad Sci, Ural Branch, Postovsky Inst Organ Synth, Ekaterinburg, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2024年 / 65卷 / 07期
关键词：
copper(II) complexes; taurine N-derivatives; complexation; CRYSTAL-STRUCTURES; EFFICIENT LIGAND; CARBOXYLATE; SULFONATE; CATALYST;
D O I：
10.1134/S0022476624070102
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel copper(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid is prepared, its structure is studied by XRD (CCDC No. 2215117). The crystal of the complex is formed by monomeric [CuLH2O]NO3 units. The metal centers of the units have an octahedral coordination environment formed by nitrogen atoms of pyridine and the amino group, oxygen atoms of the sulfo group, and water molecules located in the equatorial plane. On the axial axis, there are oxygen atoms of the sulfo groups of the neighboring ligands forming a 1D coordination polymer.
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收藏
页码：1395 / 1403
页数：9
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