SYNTHESIS AND STRUCTURE OF A COPPER(II) COMPLEX BASED ON N-2-(2-PYRIDYL)ETHYL-2-AMINOETHANESULFONIC ACID

被引:0
|
作者
Zemlyakova, E. O. [2 ]
Zharkov, G. P. [1 ]
Petrova, Y. S. [1 ]
Neudachina, L. K. [1 ]
Slepukhin, P. A. [2 ]
Aksenova, T. V. [1 ]
Pestov, A. V. [1 ,2 ]
机构
[1] Ural Fed Univ, Ekaterinburg, Russia
[2] Russian Acad Sci, Ural Branch, Postovsky Inst Organ Synth, Ekaterinburg, Russia
关键词
copper(II) complexes; taurine N-derivatives; complexation; CRYSTAL-STRUCTURES; EFFICIENT LIGAND; CARBOXYLATE; SULFONATE; CATALYST;
D O I
10.1134/S0022476624070102
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel copper(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid is prepared, its structure is studied by XRD (CCDC No. 2215117). The crystal of the complex is formed by monomeric [CuLH2O]NO3 units. The metal centers of the units have an octahedral coordination environment formed by nitrogen atoms of pyridine and the amino group, oxygen atoms of the sulfo group, and water molecules located in the equatorial plane. On the axial axis, there are oxygen atoms of the sulfo groups of the neighboring ligands forming a 1D coordination polymer.
引用
收藏
页码:1395 / 1403
页数:9
相关论文
共 50 条
  • [1] N-2-(2-pyridyl)ethyl chitosan: Synthesis in gel and sorption properties
    Pestov, A. V.
    Bratskaya, S. Yu
    Azarova, Yu A.
    Kodess, M. I.
    Yatluk, Yu G.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (04) : 713 - 718
  • [2] N-2-(2-pyridyl)ethyl chitosan: Synthesis in gel and sorption properties
    A. V. Pestov
    S. Yu. Bratskaya
    Yu. A. Azarova
    M. I. Kodess
    Yu. G. Yatluk
    Russian Journal of Applied Chemistry, 2011, 84 : 713 - 718
  • [3] N-2-(2-pyridyl)ethylpolyallylamine: synthesis in gel and sorption properties
    Pestov, A. V.
    Lakiza, N. V.
    Tissen, O. I.
    Neudachina, L. K.
    Matochkina, E. G.
    Kodess, M. I.
    Yatluk, Yu. G.
    RUSSIAN CHEMICAL BULLETIN, 2014, 63 (03) : 754 - 758
  • [4] N-2-(2-pyridyl)ethylpolyallylamine: synthesis in gel and sorption properties
    A. V. Pestov
    N. V. Lakiza
    O. I. Tissen
    L. K. Neudachina
    E. G. Matochkina
    M. I. Kodess
    Yu. G. Yatluk
    Russian Chemical Bulletin, 2014, 63 : 754 - 758
  • [5] STRUCTURE OF BIS(N-[2-(2-PYRIDYL)ETHYL]-3-ETHOXYSALICYLIDENEAMINATO)COPPER(II)
    CASTINEIRAS, A
    HILLER, W
    STRAHLE, J
    ROMERO, J
    BASTIDA, R
    SOUSA, A
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 770 - 772
  • [6] Synthesis, structure, and properties of {N,N'-bis[2-(2-pyridyl)ethyl]pyridine-2,6-dicarboxamido}copper(II)
    Chavez, FA
    Olmstead, MM
    Mascharak, PK
    INORGANIC CHEMISTRY, 1996, 35 (05) : 1410 - &
  • [7] Synthesis, Properties, and X-ray Crystal Structure of Copper(II) Complex with Bis[(2-pyridyl) methyl]-2-(2-pyridyl) ethylamine
    Choi, Ki-Young
    JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE, 2007, 51 (01): : 31 - 35
  • [8] SPECTROPHOTOMETRIC DETERMINATION OF COPPER (II) WITH N-2-(2'-PYRIDYLMETHYLENEAMINO)ETHYL-N-2-AMINOETHYLCARBODITHIOIC ACID
    ITOH, Y
    SUGAWARA, M
    KAMBARA, T
    BUNSEKI KAGAKU, 1975, 24 (09) : 571 - 574
  • [9] Ethyl N-(2-pyridyl)carbamate
    Zheng, PW
    Wang, W
    Duan, XM
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : O2970 - O2971
  • [10] N,N′-Bis[2-(2-pyridyl)ethyl]dithiooxamide
    Cui, JZ
    Zhang, D
    Pan, SW
    Cheng, P
    Liao, DZ
    Wang, GL
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O1913 - O1915