ELECTRICAL CONDUCTIVE AND MAGNETIC-PROPERTIES OF CONJUGATED TETRATHIOLATE NICKEL POLYMERS

被引：25
|
作者：
YOSHIOKA, N [1 ]
NISHIDE, H [1 ]
INAGAKI, K [1 ]
TSUCHIDA, E [1 ]
机构：
[1] WASEDA UNIV,DEPT POLYMER CHEM,TOKYO 169,JAPAN
来源：
POLYMER BULLETIN | 1990年 / 23卷 / 06期
关键词：
Organometallics--Oxidation - Polymers--Magnetic Properties;
D O I：
10.1007/BF01033109
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Three tetrathiolate (tetrathiafulvalenetetrathiolate, ethylenetetrathiolate, and butadienetetrathiolate) nickel polymers are prepared. The polymers contain mixed valence Ni ions and are ESR active based on low-spin d8 Ni (III) species. Magnetic susceptibility measurement in the range of 30-60 K suggests and antiferromagnetic interaction between the Ni ions in the polymers. Below 30K a weak ferromagnetic interaction is observed. Chemically oxidized polymers are ESR inactive, while electrical conductivity is greatly enhanced. © 1990 Springer-Verlag.
引用
收藏
页码：631 / 636
页数：6
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