Nickel ethylene tetrathiolate polymers as nanoparticles: a new synthesis for future applications?

被引：16
|
作者：
Faulmann, Christophe [1 ,2 ]
Chahine, Joe [1 ,2 ]
Jacob, Kane [1 ,2 ]
Coppel, Yannick [1 ,2 ]
Valade, Lydie [1 ,2 ]
de Caro, Dominique [1 ,2 ]
机构：
[1] CNRS, LCC, UPR 8241, F-31077 Toulouse 4, France
[2] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France
来源：
JOURNAL OF NANOPARTICLE RESEARCH | 2013年 / 15卷 / 04期
关键词：
Nanoparticles; Molecular conductors; Metal ethylene tetrathiolate; Microscopy; NMR; SOLID-STATE PROPERTIES; IONIC LIQUIDS; MAGNETIC-PROPERTIES; COORDINATION NANOPARTICLES; METAL-COMPLEXES; TEMPERATURE; CHEMISTRY; SALTS; SIZE; 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATE;
D O I：
10.1007/s11051-013-1586-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Coordination polymers (CP) based on the ethylene tetrathiolate ligand (C2S4)(4-) and Ni2+ and previously isolated as insoluble conductive powders are grown as nanoparticles (NP) using ionic liquid (IL) as stabilizing agent. The time of addition of the IL determines the morphology, and consequently the properties of the CP. The smaller (10-20 nm) and soluble NP are obtained when IL is present at the complexation step. The mechanism of growth of NP is studied. The NP size is sensitive to the amount of IL and to the reaction temperature. NPs are studied by TEM/EDX, DLS, liquid- and solid-state NMR, and conductivity.
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页数：18
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