N,N-DIALKYLCARBAMATES OF SILICON AND ALUMINUM

被引：0
|
作者：
DELLAMICO, DB
CALDERAZZO, F
DELLINNOCENTI, M
GULDENPFENNIG, B
IANELLI, S
PELIZZI, G
机构：
[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,SEZIONE CHIM INORGAN,VIA RISORGIMENTO 35,I-56126 PISA,ITALY
[2] UNIV PARMA,IST CHIM GEN,I-43100 PARMA,ITALY
[3] UNIV PARMA,CTR STRUTT DIFFRATTOMETR,CNR,I-43100 PARMA,ITALY
来源：
GAZZETTA CHIMICA ITALIANA | 1990年 / 120卷 / 12期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of SiCl4 with R2NH and carbon dioxide in a hydrocarbon solvent at atmospheric pressure and at room temperature gave the N,N-dialkylcarbamates Si(O2CNR2)4, R = Me, Et, (i)Pr; the iso-propyl derivative was studied by X-ray diffraction methods and found to be monomeric with terminally bonded monodentate carbamato groups. Aluminium bromide and NH(i)Pr2 under carbon dioxide led to Al2(O2CN(i)Pr2)6.
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页码：819 / 820
页数：2
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