HIGHLY ENANTIOSELECTIVE OXIDATION OF FERROCENYL SULFIDES

被引：42
|
作者：
DITER, P [1 ]
SAMUEL, O [1 ]
TAUDIEN, S [1 ]
KAGAN, HB [1 ]
机构：
[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,SYNTHESE ASYMETRIQUE LAB,F-91405 ORSAY,FRANCE
来源：
TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 04期
关键词：
D O I：
10.1016/0957-4166(94)80015-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oxidation of aryl or alkyl ferrocenyl sulfides by cumene hydroperoxide was investigated in presence of chiral titanium complexes. It was found that the preparation of the combination Ti((OPr)-Pr-i)(4) / DET / H2O = 1 : 2 : 1 is very sensitive to time and temperature. In suitable conditions some aryl ferrocenyl sulfoxides almost enantiomerically pure (> 99% ee) could be produced.
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收藏
页码：549 / 552
页数：4
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