Highly enantioselective oxidation of sulfides to sulfoxides by a new oxaziridinium salt

被引：45
|
作者：
del Rio, R. E. [1 ]
Wang, B. [1 ]
Achab, S. [1 ]
Bohe, L. [1 ]
机构：
[1] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 12期
关键词：
D O I：
10.1021/ol0702573
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The new oxaziridinium salt 5 (R-2 = TBDPS) is an effective reagent for the highly enantioselective oxidation of sulfides to sulfoxides with up to > 99% ee and good yields. As such, it represents a new valuable nonmetallic alternative to the existing methods for asymmetric sulfoxidation.
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收藏
页码：2265 / 2268
页数：4
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