Highly enantioselective catalytic oxidation of alkyl aryl sulfides using Mn-salen catalyst

被引：116

作者：

Kokubo, C ^{[1
]}

Katsuki, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 81281,JAPAN

来源：

TETRAHEDRON | 1996年 / 52卷 / 44期

关键词：

D O I：

10.1016/0040-4020(96)00851-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic asymmetric oxidation of sulfides was carried out by using Mn-salen complex (aS,R)-4a as a catalyst and high enantioselectivity up to 94% was achieved Enantioselectivity of the reaction was affected by the solvent used and the use of acetonitrile, ethyl propionate, or chlorobenzene generally gave good results. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：13895 / 13900

页数：6

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