SYNTHESES AND SPECTROSCOPIC CHARACTERIZATION OF STEREOISOMERS OF BIS(TERT-BUTILSULFINYL)ALKYLMETHANES

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作者
FRANCO, C
ZARRAGA, M
ZUNZA, H
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O6 [化学];
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0703 ;
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The synthesis and spectroscopic characterization of the stereoisomers of bis(tert-butilsulfinyl)methane and 1,1-bis(tert-butilsulfinyl)octane is reported. The stereoisomeric mixture of bis(tert-butilsulfinyl)methane, meso and dl pair compounds and stereoisomeric mixture of 1,1-bis(tert-butilsulfinyl)octane, were separated by chromatography and characterized by NMR techniques. The corresponding oxidation products of bis(tert-butilthio)methane: monosulfoxide, monosulfoxide-monosulfone and disulfone compounds were also synthesized.
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页码:319 / 324
页数:6
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