(1'R,2S,3R)-2-HYDROXY-2-(2-HYDROXYETHYL)-3-METHYL-GAMMA-BUTYROLACTONE

被引：2
|
作者：
KOPF, J [1 ]
SCHULZ, S [1 ]
机构：
[1] UNIV HAMBURG,INST ORGAN CHEM,D-20146 HAMBURG,GERMANY
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷
关键词：
D O I：
10.1107/S010827019400819X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The determination of the structure of the title compound, C7H12O4, allowed the unambiguous elucidation of the absolute configuration of a pheromone produced by the tropical butterfly Prittwitzia hymaenea. This unique pheromone is the 1'-epimer of the title compound. The lactone ring adopts a rather hat, almost ideal envelope conformation. The structure is stabilized by hydrogen bonds.
引用
收藏
页码：84 / 86
页数：3
相关论文
共 50 条
  • [21] SYNTHESIS AND ABSOLUTE-CONFIGURATION OF 2 DIASTEREOISOMERIC (1R,2S,3R) AND (1S,2S,3R)-2-AMINO-1-(2-FURYL)-1,3-BUTANDIOLS
    SZECHNER, B
    TETRAHEDRON, 1981, 37 (05) : 949 - 952
  • [22] UNEXPECTED TRANSFORMATION OF (2S, 3R)-METHYL 2-AZIDO-3-HYDROXY-4-PIVALOYLOXYBUTANOATE TO METHYL 2-AZIDO-4-PIVALOYLOXY-2-BUTENOATE
    TOLSTIKOV, AG
    YAMILOV, RK
    ODINOKOV, VN
    TOLSTIKOV, GA
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (01): : 233 - 234
  • [23] Chiron approach to the synthesis of (2S,3R)-3-hydroxypipecolic acid and (2R,3R)-3-hydroxy-2-hydroxymethylpiperidine from D-glucose
    Kalamkar, Navnath B.
    Kasture, Vijay M.
    Dhavale, Dilip D.
    JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (09): : 3619 - 3622
  • [24] Stereoselective synthesis of (1R,2S,3R)-camphordiamine
    Busacca, CA
    Campbell, S
    Dong, Y
    Grossbach, D
    Ridges, M
    Smith, L
    Spinelli, E
    JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (15): : 4753 - 4755
  • [25] Enantioselective synthesis of (2R,3R)- and (2S,3S)-2-[(3-chlorophenyl)-(2-methoxyphenoxy)methyl]morpholine
    Harding, WW
    Hodge, M
    Wang, ZX
    Woolverton, WL
    Parrish, D
    Deschamps, JR
    Prisinzano, TE
    TETRAHEDRON-ASYMMETRY, 2005, 16 (13) : 2249 - 2256
  • [26] Stereoselective synthesis of [2S,3R]-beta-hydroxy ornithine
    Rao, BV
    Krishna, UM
    Gurjar, MK
    SYNTHETIC COMMUNICATIONS, 1997, 27 (08) : 1335 - 1345
  • [27] Crystal structure of [(2S,3R)-3-hydroxy-phenylbutan-2-yl]pyrrolidinium chloride
    Kandhaswamy, Abirami
    Meena, K. S.
    Deepa, S.
    Murugavel, S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O758 - U411
  • [28] (3R,4S,5S)-4-hydroxy-3-methyl-5-[(2S,3R)-3-methylpent-4-en-2-yl] tetrahydrofuran-2-one
    Becker, Annika
    Schuermann, Markus
    Preut, Hans
    Hiersemann, Martin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1517 - U2536
  • [29] VERSATILE SYNTHESIS OF STEREOSPECIFICALLY LABELED D-AMINO ACIDS VIA LABELED AZIRIDINES - PREPARATION OF (2R,3S)-[3-H-2(1)]-SERINE AND (2R,3R)-[2,3-H-2(2)]-SERINE (2S,2'S,3S,3'S-[3,3'-H-2(2)]-CYSTINE AND (2S,2'S,3R,3'R)-[2,2',3,3'-H-2(4)]-CYSTINE AND (2S,3S)-[3-H-2(1)-] AND (2S,3R)-[2,3-H-2(2)]-BETA-CHLOROALANINE
    AXELSSON, BS
    OTOOLE, KJ
    SPENCER, PA
    YOUNG, DW
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (07): : 807 - 815
  • [30] An efficient asymmetric synthesis of (2S,3S)- and (2R,3R)-β-hydroxyornithine
    DeMong, DE
    Williams, RM
    TETRAHEDRON LETTERS, 2001, 42 (02) : 183 - 185
12345