Crystal structure of [(2S,3R)-3-hydroxy-phenylbutan-2-yl]pyrrolidinium chloride

被引：0

作者：

Kandhaswamy, Abirami ^{[1
]}

Meena, K. S. ^{[1
]}

Deepa, S. ^{[2
]}

Murugavel, S. ^{[3
]}

机构：

[1] Queen Marys Coll, Dept Chem, Madras 600004, Tamil Nadu, India

[2] Govt Coll Engn, Dept Phys, Salem 636011, India

[3] Thanthai Periyar Govt Inst Technol, Dept Phys, Vellore 632002, Tamil Nadu, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; salt; pyrrolidinium chloride; ionic liquids; hydrogen bonding;

D O I：

10.1107/S2056989015016916

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title molecular salt, C14H22NO+center dot Cl-, the pyrrolidinium ring adopts a twisted conformation about one of the N-C bonds. It is oriented at a dihedral angle of 42.0 (1)degrees with respect to the benzene ring. The torsion angle for the central N-C-C-Car (ar = aromatic) linkage is 163.74 (15)degrees. In the crystal, the components are linked via N -H" " "Cl and O-H center dot center dot center dot Cl" hydrogen bonds, forming zigzig chains along the b -axis direction. These chains are connected along the c axis by very weak C-H center dot center dot center dot pi interactions, forming a two-dimensional supramolecular network.

引用

页码：O758 / U411

页数：8

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