catena-Poly[[[aqua(1,10-phenanthroline-kappa N-2,N ')manganese(II)]-{mu-4,4 '-[(4-carboxybenzyl)nitrilo]dibenzoato-kappa O-4,O ':O '',O '''}] monohydrate]

被引：0
|
作者：
Hu, Jin-Song [1 ]
Jing, Lei [1 ]
Song, Xiao-Ming [1 ]
He, Jie [1 ]
机构：
[1] Anhui Univ Sci & Technol, Sch Chem Engn, Huainan 232001, Anhui, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812016819
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, {[Mn(C22H15NO6)(C12H8N2)(H2O]center dot H2O}(n), was obtained under solvothermal conditions. The Mn2+ cation exhibits a distorted pentagonal-bipyramidal MnN2O5 coordination sphere with the water O atom and one of the phenanthroline N atoms in the axial positions. The cation is bridged by the doubly deprotonated 4,4'-[(4-carboxybenzyl)nitrilo]dibenzoate ligand, generating a polymeric chain parallel to [100]. O-H center dot center dot center dot O hydrogen bonding, as well as pi-pi interactions between neighbouring phenanthroline ligands, with centroid-centroid distances of 3.695 (1) angstrom, lead to the construction of a three-dimensional network.
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页码：M650 / +
页数：11
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