ASYMMETRIC TOTAL SYNTHESIS OF ALKALOIDS AND SECO-IRIDOIDS

被引：6
|
作者：
BROWN, RT
FORD, MJ
机构：
[1] Chemistry Department, The University, Manchester
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 14期
关键词：
D O I：
10.1016/S0040-4039(00)88908-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A chiral cyclopentenolone from Michael addition of an oxazepine derived from ephedrine to a cyclopentene-1,2-dione has been converted into pure enantiomers of established synthetic precursors to alkaloids and seco-iridoids via a novel exchange which recovers the chiral auxiliary. © 1990.
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收藏
页码：2033 / 2036
页数：4
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