SYNTHESIS OF TRINUCLEAR MOLYBDENUM CLUSTER COMPLEX WITH NOVEL SKELETON, [MO3(MU-3-CCH3)(MU-3-O)(MU-C6H5COO)6(CH3OH)3]CL THROUGH BRIDGING CARBOXYLATE LIGAND SUBSTITUTION

被引：6

作者：

NAKATA, K ^{[1
]}

YAMAGUCHI, T ^{[1
]}

SASAKI, Y ^{[1
]}

ITO, T ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT CHEM, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 06期

关键词：

D O I：

10.1246/cl.1992.983

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Mo3(mu-3-CCH3)(mu-3-O)(mu-CH3COO)6(H2O)3]+ undergoes bridging acetates substitution with benzoate ions in CH3OH-CH3CN mixed solvent to give [Mo3(mu-3-CCH3)(mu-3-O)(mu-C6H5COO)6(CH3OH)3]+, which can never be synthesized in principle by the conventional direct method.

引用

页码：983 / 986

页数：4

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