A trinuclear cluster of molybdenum(IV), Mo-3(mu(3)-S)(mu(2)-S)(3)(HC2O4)(2)(C2O4)(H2O)(3)

被引：2
|
作者：
Cotton, FA [1 ]
Daniels, LM [1 ]
Shang, MY [1 ]
Llusar, R [1 ]
Schwotzer, W [1 ]
机构：
[1] UNIV JAUME 1, DEPT EXPT SCI, CASTELLO, SPAIN
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷
关键词：
D O I：
10.1107/S0108270195013928
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The three molybdenum centers in triaqua-1 kappa O;2 kappa O;3 kappa O-bis[oxalato (1--)] - 2 kappa(2)O,O '';3 kappa(2)O,O ''-oxalato (2-) - 1 kappa(2)O,O ''-mu(3)-thio-tri-mu-thio-1:2 kappa(2)S;1:3 kappa(2)S;2:3 kappa(2)S-triangulo-trimolybdenum diethanol solvate, [Mo3S4 (C2HO4)(2)(C2O4)(H2O)(3)].2C(2)H(6)O, form an equilateral triangle with an average Mo-Mo distance of 2.736 (4) Angstrom. Each Mo atom is in a distorted octahedral environment made up of two O atoms of an oxalate ligand, one O atom of a water molecule, one capping-sulfur and two bridging-sulfur ligands. The structure is further stabilized by intermolecular hydrogen bonding between the oxalate and water ligands.
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页码：835 / 838
页数：4
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