PREPARATION, RESOLUTION AND ABSOLUTE-CONFIGURATION OF 2,2'-BIPYRIDINE-3,3'-DICARBOXYLIC ACID 1,1'-DIOXIDE AND ITS ESTER

被引：25
|
作者：
TICHY, M [1 ]
ZAVADA, J [1 ]
PODLAHA, J [1 ]
VOJTISEK, P [1 ]
机构：
[1] CHARLES UNIV,DEPT INORGAN CHEM,CR-12840 PRAGUE 2,CZECH REPUBLIC
来源：
TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 06期
关键词：
D O I：
10.1016/0957-4166(95)00160-Q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title racemic acid (+/-)-1, prepared by hydrogen peroxide oxidation of 2,2'-bipyridine-3,3'-dicarboxylic acid, was resolved via the brucine salts. The absolute configuration of acid (+)-1 was determined by X-ray diffraction study of its barium salt using the Bijvoet's anomalous dispersion method. The activation energy Delta G not equal for interconversion of enantiomers of the dimethyl ester 2 was found to be -106.5 kJ/mol at 50 degrees C.
引用
收藏
页码：1279 / 1282
页数：4
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