Synthesis, Electrochemical and Fluorescent Properties of a New Zinc(Ⅱ) Complex through Self-assembly Reaction of 2,2'-Bipyridine-3,3'-dicarboxylic Acid

被引：0
|
作者：
谭雄文 [1 ,2 ]
李昶红 [1 ,3 ]
李衡峰 [1 ]
杨颖群 [2 ]
机构：
[1] School of Materials Science and Engineering,Central South University
[2] Key Laboratory of Functional Organometallic Materials of Hunan Province, Department of Chemistry and Materials Science, Hengyang Normal University
[3] Department of Chemical Engineering, Hunan Institute of Technology
来源：
Chinese Journal of Structural Chemistry | 2017年 / 36卷 / 02期
关键词：
zinc(Ⅱ) complex; crystal structure; electrochemical and fluorescent properties;
D O I：
10.14102/j.cnki.0254-5861.2011-1415
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
A new Zn(Ⅱ) complex [Zn(Phen)2(C12H6O4N2)(H2O)]·3H2O with 2,2?-bipyridine-3,3?-dicarboxylic acid and 1,10-phenanthroline(Phen) as ligands was synthesized, and the crystal data are as follows: monoclinic, space group P21/n, a=12.5581(11), b=17.3382(17), c=15.6687(14) ?, β=110.579(2)o, Mr=731.02, V=3193.9(5) ?~3, Dc=1.520 g/cm~3, Z=4, μ(Mo Kα)=0.833 mm-1, F(000)=1508, the final R=0.0431 and w R=0.0936. In the title complex, the central Zn(Ⅱ) ion is located in a distorted octahedral coordination environment. The electrochemical and fluorescent properties were studied. The title complex possesses irreversible electron transfer in the electrode reaction, and it has a strong emission peak in the range of 470~505 nm, with the excitation wavelength being 488 nm.
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页码：310 / 315
页数：6
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