SYNTHESIS OF ALLENYLKETENIMINES VIA TITANOCENE VINYLIDENE COMPLEXES

被引：22
|
作者：
DENNEHY, RD [1 ]
WHITBY, RJ [1 ]
机构：
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期
关键词：
D O I：
10.1039/c39920000035
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The intermolecular addition of in situ generated titanocene vinylidene complexes to alkynes gives titanacyclobutenes which undergo an insertion-rearrangement with tert-butyl isocyanide to afford allenylketenimines in high yield.
引用
收藏
页码：35 / 36
页数：2
相关论文
共 50 条
  • [41] Synthesis of unsymmetrical diarylselenides from arylselenium complexes of titanocene and diaryl iodonium salts
    Huang, X
    Wu, LL
    Xu, XH
    SYNTHETIC COMMUNICATIONS, 2001, 31 (12) : 1871 - 1874
  • [42] Synthesis of ruthenium vinylidene complexes with dppe ligand and their cyclopropenation reaction
    Chang, CW
    Ting, PC
    Lin, YC
    Lee, GH
    Wang, Y
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 553 (1-2) : 417 - 425
  • [43] SYNTHESIS OF ALKYNE, ALKYNYL AND VINYLIDENE RHODIUM COMPLEXES FROM ALKYNYLTRIPHENYLSILANES
    BAUM, M
    WINDMULLER, B
    WERNER, H
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (07): : 859 - 869
  • [44] REACTIONS OF DISUBSTITUTED BUTADIYNES WITH TITANOCENE COMPLEXES
    ROSENTHAL, U
    OHFF, A
    TILLACK, A
    BAUMANN, W
    GORLS, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 468 (1-2) : C4 - C8
  • [45] VINYLIDENE COMPLEXES OF TRANSITION-METALS .2. NEW METHOD OF SYNTHESIS OF VINYLIDENE COMPLEXES - CYMANTRENE DERIVATIVES CONTAINING PHENYLVINYLIDENE LIGANDS
    ANTONOVA, AB
    KOLOBOVA, NE
    PETROVSKY, PV
    LOKSHIN, BV
    OBEZYUK, NS
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 137 (01) : 55 - 67
  • [46] Bonding analysis of titanocene borane σ-complexes
    Lam, WH
    Lin, ZY
    ORGANOMETALLICS, 2000, 19 (13) : 2625 - 2628
  • [47] CHEMISTRY OF VINYLIDENE COMPLEXES .11. SYNTHESIS OF TRINUCLEAR MNFEPT COMPLEXES BY MEANS OF CONSECUTIVE ASSEMBLING OUT OF MONOMETAL AND DIMETAL VINYLIDENE PRECURSORS
    ANTONOVA, AB
    JOHANSSON, AA
    DEYKHINA, NA
    GINZBURG, AG
    KORNIYETS, ED
    KOVALENKO, SV
    PAVLENKO, NI
    PETROVSKII, PV
    RUBAYLO, AI
    SUKHINA, IA
    INORGANICA CHIMICA ACTA, 1995, 230 (1-2) : 97 - 104
  • [48] MANGANESE VINYLIDENE COMPLEXES
    BERKE, H
    HUTTNER, G
    VONSEYERL, J
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 218 (02) : 193 - 200
  • [49] Chemistry of vinylidene complexes
    Antonova, A. B.
    Chudin, O. S.
    Pavlenko, N. I.
    Sokolenko, W. A.
    Rubaylo, A. I.
    Vasiliev, A. D.
    Verpekin, V. V.
    Semeikin, O. V.
    RUSSIAN CHEMICAL BULLETIN, 2009, 58 (05) : 955 - 963
  • [50] Titanocene and zirconocene complexes in phosphinine chemistry
    Avarvari, N
    Rosa, P
    Mathey, F
    Le Floch, P
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 567 (1-2) : 151 - 155
12345