SYNTHESIS OF ALLENYLKETENIMINES VIA TITANOCENE VINYLIDENE COMPLEXES

被引：22
|
作者：
DENNEHY, RD [1 ]
WHITBY, RJ [1 ]
机构：
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期
关键词：
D O I：
10.1039/c39920000035
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The intermolecular addition of in situ generated titanocene vinylidene complexes to alkynes gives titanacyclobutenes which undergo an insertion-rearrangement with tert-butyl isocyanide to afford allenylketenimines in high yield.
引用
收藏
页码：35 / 36
页数：2
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