3-(Adamantan-1-yl)-4-[(E)-(2,6-difluorobenzylidene)amino]-1-[(4-ethylpiperazin-1-yl)methyl]-4,5-dihydro-1H-1,2,4-triazole-5-thione

被引：4
|
作者：
Al-Tamimi, Abdul-Malek S. [1 ]
Al-Abdullah, Ebtehal S. [2 ]
El-Emam, Ali A. [2 ]
Ng, Seik Weng [3 ,4 ]
Tiekink, Edward R. T. [3 ]
机构：
[1] Salman Bin Abdulaziz Univ, Coll Pharm, Dept Pharmaceut Chem, Alkharj 11942, Saudi Arabia
[2] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, Riyadh 11451, Saudi Arabia
[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[4] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 80203, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813009264
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C26H34F2N6S, the triazole ring is linked to a benzene ring via an imine bond [N=C = 1.255 (2) angstrom; conformation: E], with a dihedral angle of 25.21 (11)degrees between the rings. The 4-ethylpiperazinyl residue is folded away from the thione-S atom. In the crystal, helical supramolecular chains propagating along [010] and sustained by weak C-S center dot center dot center dot pi (triazole) interactions occur [S center dot center dot center dot centroid distance = 3.2872 (10) angstrom]. Links between these chains are of the type benzene-C-H center dot center dot center dot N(imine) and pi-pi [between centrosymmetrically related benzene rings with an inter-centroid distance of 3.9241 (15) angstrom] and result in a three-dimensional architecture.
引用
收藏
页码：O685 / +
页数：11
相关论文
共 50 条
  • [31] 3-(1-Adamantyl)-1-{[4-(2-methoxyphenyl)piperazin-1-yl]methyl}-4-methyl-1H-1,2,4-triazole-5(4H)-thione
    Al-Tamimi, Abdul-Malek S.
    Bari, Ahmed
    Al-Omar, Mohamed A.
    Alrashood, Khalid A.
    El-Emam, Ali A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1756 - U175
  • [32] 4-{3-[Hydroxy(phenyl)methyl]-5-thioxo-4,5-dihydro-1H-1,2,4-triazol-4-yl}benzenesulfonamide
    Akkurt, Mehmet
    Celik, Ismail
    Cihan, Goekce
    Capan, Gueltaze
    Buyukgungor, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2010, 66 : O974 - U3507
  • [33] 4-phenyl-3-[(1H-1,2,4-triazol-1-yl)methyl]-1H-1,2,4-triazole-5-thione
    Jian, FF
    Bai, ZS
    Li, K
    Xiao, HL
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O393 - O395
  • [34] Ethyl 4-[1-(4-bromophenyl)-3-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-4-yl-iminomethyl]phenoxyacetate
    Thamotharan, S
    Parthasarathi, V
    Sunagar, V
    Badami, B
    Schenk, KJ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1272 - O1274
  • [35] 4-(4-amino-5-thioxo-4,5-dihydro-1H-1,2,4-triazol-3-yl)pyridinium chloride
    Ren, Xiao-Yan
    Jian, Fang-Fang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1792 - U2262
  • [36] 5-(Adamantan-1-yl)-3-[(4-benzylpiperazin- 1-yl) methyl]-1,3,4-oxadiazole2(3H)-thione
    El-Emam, Ali A.
    El-Brollosy, Nasser R.
    Attia, Mohamed I.
    Said-Abdelbaky, Mohammed
    Garcia-Granda, Santiago
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2172 - +
  • [37] 1-(Adamantan-1-yl)-3-(4-fluorophenyl)thiourea
    Demirtas, Gunes
    Dege, Necmi
    Al-Shehri, Mona M.
    El-Emam, Ali A.
    El-Brollosy, Nasser R.
    Buyukgungor, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1523 - +
  • [38] 3-{4-[(2-Hydroxybenzylidene)amino]-3-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-yl}-1,3-diphenylpropan-1-one
    Wang, Wei
    Gao, Yan
    Zhang, Jing-jing
    Jia, Xiao-yu
    Wu, Wen-peng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2533 - U2079
  • [39] 5-(Adamantan-1-yl)-3[(2-methoxyethyl) sulfanyl]-4-phenyl-4H-1,2,4 triazole
    El-Emam, Ali A.
    Al-Abdullah, Ebtehal S.
    Asiri, Hanadi H.
    Chantrapromma, Suchada
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02326 - +
  • [40] 4-({(E)-[2-(But-3-en-1-yl)-1-(prop-2-en-1-yl)-4-sulfanyl-1H-imidazol-5-yl]methylidene}amino)-3-phenyl-1H-1,2,4-triazole-5(4H)-thione
    Natarajan, Sampath
    Mathews, Rita
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2828 - +
12345