3-(Adamantan-1-yl)-4-[(E)-(2,6-difluorobenzylidene)amino]-1-[(4-ethylpiperazin-1-yl)methyl]-4,5-dihydro-1H-1,2,4-triazole-5-thione

被引：4
|
作者：
Al-Tamimi, Abdul-Malek S. [1 ]
Al-Abdullah, Ebtehal S. [2 ]
El-Emam, Ali A. [2 ]
Ng, Seik Weng [3 ,4 ]
Tiekink, Edward R. T. [3 ]
机构：
[1] Salman Bin Abdulaziz Univ, Coll Pharm, Dept Pharmaceut Chem, Alkharj 11942, Saudi Arabia
[2] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, Riyadh 11451, Saudi Arabia
[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[4] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 80203, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813009264
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C26H34F2N6S, the triazole ring is linked to a benzene ring via an imine bond [N=C = 1.255 (2) angstrom; conformation: E], with a dihedral angle of 25.21 (11)degrees between the rings. The 4-ethylpiperazinyl residue is folded away from the thione-S atom. In the crystal, helical supramolecular chains propagating along [010] and sustained by weak C-S center dot center dot center dot pi (triazole) interactions occur [S center dot center dot center dot centroid distance = 3.2872 (10) angstrom]. Links between these chains are of the type benzene-C-H center dot center dot center dot N(imine) and pi-pi [between centrosymmetrically related benzene rings with an inter-centroid distance of 3.9241 (15) angstrom] and result in a three-dimensional architecture.
引用
收藏
页码：O685 / +
页数：11
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