UNUSUAL REACTION OF GRIGNARD-REAGENTS WITH BIS(TRIFLUOROMETHYL)DISULFIDE

被引：16

作者：

MUNAVALLI, S ^{[1
]}

ROSSMAN, DI ^{[1
]}

ROHRBAUGH, DK ^{[1
]}

FERGUSON, CP ^{[1
]}

机构：

[1] USA,EDGEWOOD RES DEV & ENGN CTR,ABERDEEN PROVING GROUND,MD 21010

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 61卷 / 1-2期

关键词：

D O I：

10.1016/S0022-1139(00)80425-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Simultaneous scission of the C-S and S-S bonds of bis(trifluoromethyl)disulfide occurs on treatment with Grignard reagents at -78-degrees-C and gives rise to unsymmetrical disulfides and sulfides as well as alkyl sulfides. Under similar experimental conditions, alkyl disulfides are recovered unreacted. Probable mechanisms of the cleavage reactions are presented.

引用

页码：147 / 153

页数：7

共 50 条

[31] THE MONO-ALKYLDECYANATION OF TETRAFLUOROTEREPHTHALONITRILE BY REACTION WITH GRIGNARD-REAGENTS
MILNER, DJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 302 (02) : 147 - 152
[32] REACTION OF ISOPROPYLPHENYLKETONE WITH OPTICALLY-ACTIVE GRIGNARD-REAGENTS
LARDICCI, L
CAPORUSSO, AM
GIACOMELLI, GP
CHIMICA & L INDUSTRIA, 1975, 57 (07): : 498 - 498
[33] THE REACTION OF FLUORENETHIONE S-TOSYLIMIDE WITH GRIGNARD-REAGENTS
SAITO, T
NAKANE, M
MOTOKI, S
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (05) : 1429 - 1430
[34] STUDIES ON THE REACTION OF 3-CYANOPYRIDINE WITH GRIGNARD-REAGENTS
GAO, FL
JIAO, KF
DING, ZK
SONG, HQ
ACTA CHIMICA SINICA, 1987, 45 (09) : 922 - 925
[35] THE REACTION OF ETHYL ALPHA-SILYLACETATES WITH GRIGNARD-REAGENTS
HERNANDEZ, D
LARSON, GL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 183 (MAR): : 164 - ORGN
[36] A DETAILED DESCRIPTION OF THE MECHANISM OF REACTION OF GRIGNARD-REAGENTS WITH KETONES
ASHBY, EC
PURE AND APPLIED CHEMISTRY, 1980, 52 (03) : 545 - 569
[37] SELF-CONDENSATION REACTION OF ALKYLBENZOTHIAZOLES WITH GRIGNARD-REAGENTS
BABUDRI, F
CIMINALE, F
FLORIO, S
TETRAHEDRON LETTERS, 1984, 25 (19) : 2051 - 2054
[38] GRIGNARD REACTION AND PRODUCTS .5. REDUCTION OF KETOXIMES TO AZIRIDINES WITH GRIGNARD-REAGENTS
IMAI, K
KAWAZOE, Y
TAGUCHI, T
CHEMICAL & PHARMACEUTICAL BULLETIN, 1976, 24 (05) : 1083 - 1089
[39] MECHANISM OF THE GRIGNARD ADDITION-REACTION .15. THE REACTION OF GRIGNARD-REAGENTS WITH BENZYLPYRIDINIUM CHLORIDE
HOLM, T
ACTA CHEMICA SCANDINAVICA, 1991, 45 (03): : 276 - 279
[40] STRUCTURAL ASPECTS OF GRIGNARD-REAGENTS
HOLLOWAY, CE
MELNIK, M
COORDINATION CHEMISTRY REVIEWS, 1994, 135 : 287 - 301

← 1 2 3 4 5 →