UNUSUAL REACTION OF GRIGNARD-REAGENTS WITH BIS(TRIFLUOROMETHYL)DISULFIDE

被引：16
|
作者：
MUNAVALLI, S [1 ]
ROSSMAN, DI [1 ]
ROHRBAUGH, DK [1 ]
FERGUSON, CP [1 ]
机构：
[1] USA,EDGEWOOD RES DEV & ENGN CTR,ABERDEEN PROVING GROUND,MD 21010
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 61卷 / 1-2期
关键词：
D O I：
10.1016/S0022-1139(00)80425-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Simultaneous scission of the C-S and S-S bonds of bis(trifluoromethyl)disulfide occurs on treatment with Grignard reagents at -78-degrees-C and gives rise to unsymmetrical disulfides and sulfides as well as alkyl sulfides. Under similar experimental conditions, alkyl disulfides are recovered unreacted. Probable mechanisms of the cleavage reactions are presented.
引用
收藏
页码：147 / 153
页数：7
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