A ONE-POT SYNTHESIS OF CYCLOPROPANES FROM AROMATIC-ALDEHYDES AND STYRENE VIA IRON CARBENE COMPLEXES

被引:2
|
作者
VARGAS, RM [1 ]
HOSSAIN, MM [1 ]
机构
[1] UNIV WISCONSIN,DEPT CHEM,MILWAUKEE,WI 53211
关键词
CATALYSIS; CYCLOPROPANATION; IRON COMPLEXES; CARBENE COMPLEXES;
D O I
10.1016/0020-1693(94)03981-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A one-pot preparation of cyclopropanes from aromatic aldehydes and styrene via iron carbene complexes is reported. The preparation consisted of a sequence of reactions, involving initial addition of aldehyde to the Fp anion, followed by chlorotrimethylsilane and finally styrene in the presence of trimethylsilyltriflate.
引用
收藏
页码:159 / 160
页数:2
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