ELABORATION AND PHYSICAL-CHEMICAL PROPERTIES OF SOME NICKEL (III) OXIDES

被引：0
|
作者：
BYEON, SH [1 ]
DEMAZEAU, G [1 ]
CHOY, JH [1 ]
HAGENMULLER, P [1 ]
机构：
[1] SEOUL NATL UNIV,COLL NAT SCI,DEPT CHEM,SEOUL 151742,SOUTH KOREA
来源：
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II | 1991年 / 312卷 / 01期
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D O I：
暂无
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Trivalent nickel has been stabilized in the A0.5La1.5Zn0.5Ni0.5O4(A = Sr and Ba) lattices with K2NiF4-type structure. A comparison of the EPR spectra for Sr0.5La1.5M0.5Ni0.5O4(M = Mg and Z(n)) has shown the influence of the competing M - O bonds in the perovskite-type planes on the local distortion of the (NiO6) octahedral sites. IR spectroscopy confirmed that the (A0.5La1.5) - O bonds along the c-axis are weaker when A = Ba, resulting in stronger (Ni - O)c bonds.
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页码：37 / 42
页数：6
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