ASYMMETRIC REACTIONS CATALYZED BY CHIRAL METAL COMPLEXES .67. SYNTHESIS OF (BETA-N-SULFONYLAMINOALKYL)PHOSPHINES AND THEIR USE IN PALLADIUM-MEDIATED ASYMMETRIC-SYNTHESIS

被引：0
|
作者：
SAKURABA, S [1 ]
OKADA, T [1 ]
MORIMOTO, T [1 ]
ACHIWA, K [1 ]
机构：
[1] UNIV SHIZUOKA, SCH PHARMACEUT SCI, SHIZUOKA 422, JAPAN
来源：
CHEMICAL & PHARMACEUTICAL BULLETIN | 1995年 / 43卷 / 06期
关键词：
CATALYTIC ASYMMETRIC HYDROSILYLATION; CATALYTIC ASYMMETRIC HECK-TYPE HYDROARYLATION; PALLADIUM COMPLEX; AMINOPHOSPHINE;
D O I：
暂无
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
A series of (beta-N-sulfonylaminoalkyl)phosphine ligands has been developed and employed for asymmetric palladium-catalyzed hydrosilylation and Heck-type hydroarylation, affording up to 72% ee and 90% yield.
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页码：927 / 934
页数：8
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