ASYMMETRIC REACTIONS CATALYZED BY CHIRAL METAL COMPLEXES .67. SYNTHESIS OF (BETA-N-SULFONYLAMINOALKYL)PHOSPHINES AND THEIR USE IN PALLADIUM-MEDIATED ASYMMETRIC-SYNTHESIS

被引：0

作者：

SAKURABA, S ^{[1
]}

OKADA, T ^{[1
]}

MORIMOTO, T ^{[1
]}

ACHIWA, K ^{[1
]}

机构：

[1] UNIV SHIZUOKA, SCH PHARMACEUT SCI, SHIZUOKA 422, JAPAN

来源：

CHEMICAL & PHARMACEUTICAL BULLETIN | 1995年 / 43卷 / 06期

关键词：

CATALYTIC ASYMMETRIC HYDROSILYLATION; CATALYTIC ASYMMETRIC HECK-TYPE HYDROARYLATION; PALLADIUM COMPLEX; AMINOPHOSPHINE;

D O I：

暂无

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

A series of (beta-N-sulfonylaminoalkyl)phosphine ligands has been developed and employed for asymmetric palladium-catalyzed hydrosilylation and Heck-type hydroarylation, affording up to 72% ee and 90% yield.

引用

页码：927 / 934

页数：8

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