ISOTHIOCYANATO COMPLEXES OF RHENIUM .5. TRANS-BIS(ISOTHIOCYANATO)(METHOXY)(PHENYL-IMIDO)BIS(TRIPHENYLPHOSPHINE)RHENIUM(V)

被引:10
|
作者
HUBENER, R
ABRAM, U
STRAHLE, J
机构
关键词
D O I
10.1107/S0108270195000564
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound consists of well separated molecules of [Re(C6H5N)(CH3O)(NCS)(2)(C18H15P)(2)]. The Re atom is six-coordinate in a distorted octahedral environment. The two triphenylphosphine ligands are arranged trans to each other and there is a methoxy group in the position trans to the phenylimido group. The Re-NPh distance is 1.744(4) Angstrom and the NCS ligands are coordinated via the N atom.
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页码:1284 / 1286
页数:3
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